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Jennifer Garner & Ben Affleck
Set Where They Met: "Daredevil," but they were both seeing other people at the time
Relationship Status: Married with two daughters
Repeat Offender(s): Garner first married her "Felicity" co-star Scott Foley, but sought a divorce in 2003, amidst rumors of infidelity with her "Alias" co-star Michael Vartan. They also became a couple, but confirmed splitting around the time she started seeing Affleck publicly.