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Jude Law & Sienna Miller
Set Where They Met: "Alfie," in which his character romances hers
Relationship Status: Broken engagement after it was revealed he was sleeping with his children's nanny. They got back together in 2009 but broke up again in 2011.
Repeat Offender(s): Law met his wife, Sadie Frost, on the set of the movie "Shopping." They have four children together and divorced after he started seeing Miller.