'Chuck' vs. the Guest Stars: The show's best guests

(NBC)
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Matthew Bomer as Bryce Larkin

First seen in: "Pilot"

Without Bryce Larkin, there would be no "Chuck." Before he moved on to USA's "White Collar," Bomer had a recurring part as Chuck's (Zachary Levi) college rival, a CIA agent who sent the original Intersect to Chuck. He later stirred the romantic pot when he returned to work with his ex-partner/lover Sarah (Yvonne Strahovski).

-- Rick Porter, Zap2it